Analytical characterization of cadmium cyanamide in CdS thin films and bulk precipitates produced from CBD process in pilot plant

CdS thin films and bulk precipitates were obtained by chemical bath deposition (CBD) in a well-closed reactor. X-ray diffraction spectroscopy, Fourier transform infrared spectroscopy, thermal analysis, elemental analysis and leaching have been used to characterize solids and thin films. It has been shown that the proportion of cadmium cyanamide in solids may vary from about 50% to 2% according to physicochemical conditions in solution (time after CBD, ammonia concentration) and that CdO results from CdCN₂ after air annealing of thin films. This last step also increases the crystallinity of the films.     

古老的铁艺再次辉煌

铁艺实用美观，唤起人们的怀旧情怀，从公共场所到家居装饰，应用广泛。介绍铁艺选择、使用、维护与保养知识，分析，预测铁艺的市场前景。     

Shear-induced crystallization of poly(phenylene sulfide)

The crystalline morphology of poly(phenylene sulfide) (PPS) isothermally crystallized from the melt under shear has been observed by polarized optical microscope (POM) equipped with a CSS450 hot-stage. The shish–kebab-like fibrillar crystal structure is formed at a higher shear rate or for a longer shear time, which is ascribed to the tight aggregation of numerous oriented nuclei in the direction of shear. The crystallization induction time of PPS decreases with the shear time, indicating that the shear accelerates the formation of stable crystal nuclei. Under shear, the increase of spherulite growth rate results from highly oriented chains. The melting behavior of shear-induced crystallized PPS performed by differential scanning calorimetry (DSC) shows multiple melting peaks. The lower melting peak corresponds to melting of imperfect crystal, and the degree of crystal perfection decreases as the shear rate increases. The higher melting peak is related to the orientation of molecular chains. These oriented molecular chains form the orientation nuclei which have higher thermal stability than the kebab-like lamellae that are developed later. A new model based on the above observation has been proposed to explain the mechanism of shish–kebab-like fibrillar crystal formation under shear flow.     

某硅线石矿石选别中除铁研究

针对矿石中硅线石微细嵌布，铁矿物嵌布亦较细。且有近二分之一铁在非金属矿物晶格之中，除铁难的特点，通过试验研究对比采用一段磨矿磁选除铁后磁尾浮选富集硅线石．浮选精矿再磨后酸浸再除铁的工艺方法，获得了理想的除铁效果，使硅线石精矿质量达到较高品质。     

转炉入炉铁水温度低的原因分析及其对炼钢的影响

系统分析了新钢公司一钢厂转炉入炉铁水温度低的原因及铁水温度对炼钢的影响，提出了提高铁水温度的措施及转炉应对低温铁水的办法。     

A branch-and-price algorithm to solve the molten iron allocation problem in iron and steel industry

The molten iron allocation problem (MIAP) is to allocate molten iron from blast furnaces to steel-making furnaces. The allocation needs to observe the release times of the molten iron defined by the draining plan of the blast furnaces and the transport time between the iron-making and steel-making stages. Time window constraints for processing the molten iron must be satisfied to avoid freezing. The objective is to find a schedule with minimum total weighted completion time. This objective reflects the practical consideration of improving steel-making efficiency and reducing operation cost caused by the need for reheating. Such a problem can be viewed as a parallel machine scheduling problem with time windows which is known to be NP-hard. In this paper, we first formulate the molten iron allocation problem as an integer programming model and then reformulate it as a set partitioning model by applying the Dantzig–Wolfe decomposition. We solve the problem using a column generation-based branch-and-price algorithm. Since the subproblem of column generation is still NP-hard, we propose a state-space relaxation-based dynamic programming algorithm for the subproblem. Computational experiments demonstrate that the proposed algorithm is capable of solving problems with up to 100 jobs to optimality within a reasonable computation time.     

���������ɹ���ߺ�����������ѹ�����㷽����MDT���Է���

川东北飞仙关组高含硫气藏气井在完井测试过程中，压力测点位置与产层中部的距离较大，需将压力数据用气柱压力计算公式折算后再进行试井分析解释。文章以质量、动量和能量三大守恒方程和状态方程为基础，考虑了流动气柱的动能损失以及井筒和地层中复杂的传热机理，推导出计算单相气流在井筒不同部位压力和温度的方法。以坡2井为例，应用目前最新的模块化动态地层测试器MDT地层测试技术，对折算的压力进行了验证和对比分析。结果表明，应用文中的压力计算方法，完全可以满足解释的压力数据精度。另外，在没有进行完井测试前利用MDT测压资料确定地层压力等储层参数是较为直接和可靠的方法。同时此法对川东北飞仙关组高含硫气藏的开发动态监测以控制元素硫在井底和井筒的沉积具有十分重要的指导意义。     

电熨斗底板水溶性聚四氟乙稀真空静电喷涂工艺

介绍了电熨斗底板真空静电喷涂的工作原理。说明了电晕放电在底板真空静电喷涂中的作用。分析了氟涂料微粒的带电过程及影响因素。这个工艺对产品质量提高的作用进行了分析。     

化学模式识别法在钢铁工业中的若干应用

本文涉及一种崭新的非函数数据处理法及其在工业诊断和优化中的应用。并对其进行要因分析和优化决策的原理作了介绍。结合钢铁工业生产中的实例进行了分析。还探讨了该方法在钢铁工业中应用的意义。     

抽油机球铁齿轮的化学成分及生产工艺

为提高抽油机减速器齿轮铸件的机械性能，提出以Sn代替Mo作为合金元素，并通过试验确定了合理的Si、Cu、Sn的加入量。指出Si加入量应控制在1．9％－2．1％范围内，同时加入0．36％～0．9％的Cu和0．025％～0．07％的Sn，可保证球铁的强度和延伸率都满足QT700－2的要求。鉴于试件与实际铸件的表面硬度有一定的差值，为提高铸件表面硬度，进行了余热正火试验，并给出了铸件在铸型内的时间－冷却温度曲线。最后根据球铁化学成分的选择结果，进行了齿轮生产试验。